Burlington or one of it s surrounding communities would probably be the best fir for you. UVM and other colleges are in the area, and since it is VT s largest city, it would probably be you best bet at finding work. Great city with lots of younger people.
your best choice might be burlington for jobs, schools, and people close to your age---BUT the catch about living in burlington (or vermont) is that jobs are very few and living costs are pretty high--also, most of the people are either college kids, ski bums, hippies and white trash---i vive near by in maine and know vermont very well...you might want to consider portland, maine--i know alot of vermonters who moved here to get away from vermont
These are the top five cities in Vermont for families to live in. Burlington, Washington, Brattleboro, Bennington, Albany. I would do research on these five and see which one you like the best.